吸附反应时间对除草剂阿特拉津吸附行为的影响

采用批量动态实验方法,对潮土中阿特拉津吸附特征随吸附反应时间变化进行了研究。结果表明,土壤吸附的阿特拉津量随反应时间的变化符合双曲线函数关系。在50μg·L-1～2000μg·L-1浓度系列下,在48h内,土壤颗粒对阿特拉津的吸附属于快反应,土壤吸附的阿特拉津量随吸附反应时间呈指数上升,为吸附实验结束(168h)时土壤吸附阿特拉津总量的58%到90%。当吸附反应时间超过48h后,随反应时间增加,土壤吸附阿特拉津量差异变化不显著。阿特拉津在潮土颗粒和土壤溶液中的相分配可用Freundlich方程描述。吸附容量因子Kf与吸附反应时间之间有极显著的线性正关系(r2=0.9063**,p<0.0001)。无量纲的非线性因子n与吸附反应时间之间也具有显著的线性负关系(r2=0.5666*,p=0.0192)。     

西双版纳民族村寨土地利用的景观影响

采用参与性农村评估法 ,并结合地方农业统计年鉴 ,从村级水平对西双版纳巴卡小寨和大卡老寨 2个民族村寨土地利用的景观影响作了初步调查与分析。结果表明 ,人多地少的巴卡小寨因无大面积的公益林等自然景观而使其人为干扰强度指数为 3.196 5 ,较大卡老寨强烈 ;受干扰景观中的粮食作物地和经济作物园斑块较多 ,景观破碎度分别为 0 .0 6 92和 0 .0 980hm-2 ,均大于大卡老寨。大卡老寨因为具有公益林、风景林和水体 ,其景观多样性为 1.4 5 95 ,以公益林、经济作物园和粮食作物地为优势景观 ;大卡老寨景观均匀度和优势度分别为 0 .6 6 4 2和 0 .7377,均大于巴卡小寨。 2个村寨的粮食作物地和经济作物园面积较大 ,表明粮食生产与经济作物种植是山区发展的出路所在 ,而水田面积的扩大和稳定有利于提高人口承载力。各景观类型的规模因受市场、技术等方面的影响而逐年波动 ,但从长时间来看又趋于稳定。民族文化政策和市场对 2个村寨土地利用和景观格局影响较大。     

Description and sensitivity analysis for the LESV model: Water quality variables and the balance of organisms in a fjordic region of restricted exchange

In this paper we describe a new ecological model for Regions of Restricted Exchange (RRE), such as fjords, estuaries, rias and lagoons. The model is intended to simulate the impact of external nutrient input on microplankton (phytoplankton plus pelagic microheterotrophs) in RREs. We have implemented the model with the practical purpose of finding a safe limit to the capacities of RRE to assimilate fish-farm waste. Sea-cage farming of fish is increasing in fjords in northern and southern hemispheres, and its external nutrient input can lead to environmental problems such as eutrophication and deoxygenation. The model includes a physical system of three layers with exchanges driven by tidal movement, freshwater input, wind stirring. The biological part includes two microplankton compartments, each parameterizing a microbial loop and each containing chlorophyll. The first compartment represents diatoms and associated heterotrophs, and the second compartment represents flagellates and associated heterotrophs. As well as the balance of these organisms, the model simulates concentrations of nutrient N, P, and Si, dissolved oxygen, and water transparency. Chlorophyll and nutrient change are linked by yields (q  ). Losses of microplankton to grazing by mesozooplankton or benthos are simulated by a temperature-dependent grazing pressure acting on a mean loss (_L0)$(L_0)$. The model also includes the ability to simulate point source inputs of nutrients or organic matter and a generic tracer with first order decay. Sea-cage fish-farms exemplify such point sources. In order to explore model behaviour, we included inputs from a 1500 tonnes salmon farm multiplied by a factor (γ)$(\gamma )$. We carried out sensitivity analysis to identify the most influential model parameters and forcing variables in the case of the shallow Scottish fjord, Loch Creran, in 1975 before the introduction of salmon farming. We tested the model fit to this pristine state (γ=0)$(\gamma =0)$, using Major Axis Regression of simulated variables on observed variables. The model successfully follows the seasonal cycles of chlorophyll (summer over both microplanktons) and the limiting nutrients (P, N). The sensitivity analysis identified three sets of key parameters: (γ)$(\gamma )$ and other fish-farm coefficients, which control farm waste effects on an RRE; (_L0)$(L_0)$ parameters for each microplankton, which link these to the rest of the ecosystem and which have implications for future inclusion of shellfish farming in the model and, chlorophyll yields from nutrients (q), which are crucial for the predication of eutrophication and the ecological understanding of the model.     

模拟酸雨对森林红壤中铝的溶出及不同土层酸度变化的影响

为进一步探明酸沉降对森林红壤及生态环境的影响，模拟长沙地区降水酸度及离子组成，采用浸泡试验对两种森林红壤活性铝的释出及土壤理化性质的变化进行了研究。结果表明，模拟酸雨浸泡初期，土壤活性铝的释出量随浸泡次数的增加而增加，原始土壤pH值愈低，活性铝释出愈多；强酸度、高离子浓度（AR4）模拟酸雨对土壤中活性铝的溶出量远大于基础酸雨（AR3）及弱酸、低离子浓度酸雨（AR2）和对照酸雨（AR1）。模拟酸雨酸度愈大，对土壤pH值的影响愈明显，不同土层间，以A层土壤pH值下降最明显，B、C层土壤则下降较小。模拟酸雨模拟浸泡土壤25年后，土壤阳离子交换量均有不同程度下降，有机质含量高，原土壤阳离子交换量大的土壤下降幅度也大。     

Leaf extracellular ascorbate in relation to O(3) tolerance of two soybean cultivars

Soybean [Glycine max (L.) Merr.] cultivars Essex and Forrest that exhibit differences in ozone (O(3)) sensitivity were used in greenhouse experiments to investigate the role of leaf extracellular antioxidants in O(3) injury responses. Charcoal-filtered air and elevated O(3) conditions were used to assess genetic, leaf age, and O(3) effects. In both cultivars, the extracellular ascorbate pool consisted of 80-98% dehydroascorbic acid, the oxidized form of ascorbic acid (AA) that is not an antioxidant. For all combinations of genotype and O(3) treatments, extracellular AA levels were low (1-30nmolg(-1) FW) and represented 3-30% of the total antioxidant capacity. Total extracellular antioxidant capacity was twofold greater in Essex compared with Forrest, consistent with greater O(3) tolerance of Essex. The results suggest that extracellular antioxidant metabolites in addition to ascorbate contribute to detoxification of O(3) in soybean leaves and possibly affect plant sensitivity to O(3) injury.     

泥炭树脂颗粒对水溶液中十二烷基苯磺酸钠的去除

泥炭树脂颗粒对水溶液中十二烷基苯磺酸钠 (SDBS)具有很好的去除效果。数据分析表明 ,Freundlich和 Langmuir吸附等温方程可以很好地描述这一过程。通过 L angmuir方程计算出颗粒对 SDBS的最大吸附量为 3 3 .3 3 mg·g- 1。在试验条件下 ,吸附量随着 SDBS的初始浓度增加而增加 ,当溶液的初始 p H在 4～ 8的范围时 ,颗粒对 SDBS吸附量变化很小。溶液的初始浓度对吸附速率产生明显影响 ,浓度越低吸附速率越快 ,达到吸附平衡所需的时间越短。准二级动力学模型能够很好地描述颗粒对 SDBS的吸附过程。     

哑铃湾网箱养殖可持续容量研究

在相关养殖容量研究的基础上,提出了养殖环境容量和可持续养殖容量的概念和内涵.以哑铃湾网箱养殖为例,建立了考虑时间累积效应后的养殖环境容量和考虑了社会、经济和环境综合效益后的可持续养殖容量计算模型.估算了在10年时段内哑铃湾网箱养殖环境容量和可持续养殖容量.结果表明,哑铃湾网箱养殖最优环境容量为每年4.11万箱,可持续养殖容量为每年3.45万箱.     

A NEW METHOD FOR ESTIMATING FUTURE RESERVOIR STORAGE CAPACITIES1

ABSTRACT: A new method has been developed for estimating future reservoir storage capacities, allowing for sediment deposition and compaction. Reservoir sedimentation surveys for 117 reservoirs, conducted by the Illinois State Water Survey over the past 60 years, were used to determine regional constants K to represent the severity of sediment deposition in the reservoirs. More than half of the 82 water supply reservoirs investigated had records of reservoir sedimentation surveys, and their K values were calculated by using data from those sediment surveys. The average K values of the remaining non-surveyed water supply reservoirs were estimated from the regional distribution of the K values. Other important factors considered in the estimation of future reservoir storage capacities are the trap efficiency of the reservoirs and the variation of density of sediment deposits due to compaction. The model can also be used for analyzing the economics of alternative sites and of design features that can be incorporated in dams for reducing reservoir sedimentation.     

ON THE CAPACITY-EXPANSION OF DESALINATION PLANTS AND STORAGE TANKS1

ABSTRACT A mathematical programming model is structured to find the optimal time and capacity expansion path of desalination plants and storage tanks for a hypothetical community which depends on desalination as its sole, or major, water supply source. The objective is to determine the least costly combination of sues and times of installation (of both desalting plants and storage tanks) which can meet a rising water demand over a finite planning horizon. The optimality criterion used in the model is based on two major economic elements: the economies of scale inherent in such facilities and the time-value of money represented by the interest rate, the former favoring large capacities and the latter small capacities. The model is applied using three population growth patterns and two interest rates. The water demand components for every year in the planning period are computed using empirical formulas which are based on population and other basic data. The model is solved for each of the above cases with the aid of a computer program based on the method of feasible conjugate directions. The results clearly reflect the balance between the economies of scale and the time-value of money under every demand growth function.     

资源-环境双重约束下的区域生态效率的时序特征——以广西壮族自治区为例

为了探讨资源—环境双重约束下我国生态赤字地区资源环境绩效水平,利用生态脆弱指数和资源环境绩效指数（REPI）对地处珠江三角洲的广西资源环境绩效进行了系统分析和比较研究。结果表明：尽管资源环境绩效水平从2000年的72.4上升为2007年的116.1,但趋势并不明显,资源环境综合绩效水平在全国的第24—26位徘徊。综合绩效指数、SO2排放绩效指数、工业固体废弃物排放绩效指数和生物资源指数呈现＂N＂型变动,水污染指数下呈＂∧＂变动态势,大气污染指数呈现＂W＂型剧烈变动,生态承载力处于超载状态,生态脆弱性趋势没有明显改变。资源消耗和污染物排放的下降态势并不稳定。1995—2007年,广西区域环境水平呈下降趋势,区域环境水平和资源转化效率呈剧烈变动的下降趋势,抗逆水平和生态保护指数有所提高,土地资源指数呈现下降态势,排放强度指数下降明显,生态脆弱指数保持恒定,气候变异指数呈波浪状变动,环境治理指数呈剧烈变动。广西面临生态环境的整体不稳定性和对外力干预敏感性的双重压力。广西应发挥地处泛珠三角的地缘优势和辐射＂东盟＂的区位优势,加大结构调整和制度创新力度,缩短目前资源密集型的发展阶段,改善生态效率和承载力,提升广西在泛珠江三角洲地区的综合竞争力。